Endian-ness in FAT32
Endian-ness is about byte ordering. We have two types: big endian and little endian.
Suppose we see the following, which represents the bytes per sector.
We have two ways to interpret this number, either 0x00 02 or 0x02 00
Big Endian
0x0002 = 2 bytes
Little Endian
0x0200 = 512 bytes
As in FAT32, little Endian is used. Therefore, the number of bytes per sector is 512 bytes.